Main Group Catalysis: Cationic Si(II) and Ge(II) Compounds as Catalysts in Organosilicon Chemistry
نویسندگان
چکیده
Cyclopentadienyl (Cp)-coordinated cationic Si(II) (1) and Ge(II) compounds (2) are a new class of catalysts for various transformations in organosilicon chemistry. This review demonstrates that these effectively catalyze technically important reactions, such as the hydrosilylation carbon-carbon multiple bonds types siloxane-coupling e.g., Piers-Rubinsztajn reaction oxidative siloxane coupling reaction. Whereas sensitive to air moisture, corresponding bench stable, thus offering further advantages. The contribute growing need substitution transition metals heavier main group by their lighter congeners, especially industrially relevant
منابع مشابه
Contemporary organosilicon chemistry
Editorial for the Thematic Series on Contemporary Organosilicon Chemistry.
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ژورنال
عنوان ژورنال: Reactions
سال: 2021
ISSN: ['2624-781X']
DOI: https://doi.org/10.3390/reactions2040028