Main Group Catalysis: Cationic Si(II) and Ge(II) Compounds as Catalysts in Organosilicon Chemistry

نویسندگان

چکیده

Cyclopentadienyl (Cp)-coordinated cationic Si(II) (1) and Ge(II) compounds (2) are a new class of catalysts for various transformations in organosilicon chemistry. This review demonstrates that these effectively catalyze technically important reactions, such as the hydrosilylation carbon-carbon multiple bonds types siloxane-coupling e.g., Piers-Rubinsztajn reaction oxidative siloxane coupling reaction. Whereas sensitive to air moisture, corresponding bench stable, thus offering further advantages. The contribute growing need substitution transition metals heavier main group by their lighter congeners, especially industrially relevant

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ژورنال

عنوان ژورنال: Reactions

سال: 2021

ISSN: ['2624-781X']

DOI: https://doi.org/10.3390/reactions2040028